This postulation can be further proven by the UV-vis spectra of the PFO-DBT nanorod
bundles prepared at 500 and 1,000 rpm. With the implementation of spin coating rates of 500 and 1000 rpm, the absorption band at long wavelength are blueshifted at about 12 and 32 nm, respectively. Figure 7 Optical spectra of the PFO-DBT nanorod bundles. (a) UV-vis absorption spectra. (b) Photoluminescence spectra. The photoluminescence (PL) spectra of the PFO-DBT nanorod bundles synthesized at different spin coating rates are shown in Figure 7b. The emission of the fluorene segment which normally lied between 400 and 550 nm [2, 5, 6] is not recorded by all of the spectra. It indicates that the fluorene unit has been completely quenched, and an www.selleckchem.com/products/bmn-673.html efficient energy transfer from the PFO segments to the DBT units has occurred. The redshift of PL emission of the DBT units (shown by arrow) that are presented by the denser PFO-DBT nanorod {Selleck Anti-infection Compound Library|Selleck Antiinfection Compound Library|Selleck Anti-infection Compound Library|Selleck Antiinfection Compound Library|Selleckchem Anti-infection Compound Library|Selleckchem Antiinfection Compound Library|Selleckchem Anti-infection Compound Library|Selleckchem Antiinfection Compound Library|Anti-infection Compound Library|Antiinfection Compound Library|Anti-infection Compound Library|Antiinfection Compound Library|Anti-infection Compound Library|Antiinfection Compound Library|Anti-infection Compound Library|Antiinfection Compound Library|Anti-infection Compound Library|Antiinfection Compound Library|Anti-infection Compound Library|Antiinfection Compound Library|Anti-infection Compound Library|Antiinfection Compound Library|Anti-infection Compound Library|Antiinfection Compound Library|Anti-infection Compound Library|Antiinfection Compound Library|buy Anti-infection Compound Library|Anti-infection Compound Library ic50|Anti-infection Compound Library price|Anti-infection Compound Library cost|Anti-infection Compound Library solubility dmso|Anti-infection Compound Library purchase|Anti-infection Compound Library manufacturer|Anti-infection Compound Library research buy|Anti-infection Compound Library order|Anti-infection Compound Library mouse|Anti-infection Compound Library chemical structure|Anti-infection Compound Library mw|Anti-infection Compound Library molecular weight|Anti-infection Compound Library datasheet|Anti-infection Compound Library supplier|Anti-infection Compound Library in vitro|Anti-infection Compound Library cell line|Anti-infection Compound Library concentration|Anti-infection Compound Library nmr|Anti-infection Compound Library in vivo|Anti-infection Compound Library clinical trial|Anti-infection Compound Library cell assay|Anti-infection Compound Library screening|Anti-infection Compound Library high throughput|buy Antiinfection Compound Library|Antiinfection Compound Library ic50|Antiinfection Compound Library price|Antiinfection Compound Library cost|Antiinfection Compound Library solubility dmso|Antiinfection Compound Library purchase|Antiinfection Compound Library manufacturer|Antiinfection Compound Library research buy|Antiinfection Compound Library order|Antiinfection Compound Library chemical structure|Antiinfection Compound Library datasheet|Antiinfection Compound Library supplier|Antiinfection Compound Library in vitro|Antiinfection Compound Library cell line|Antiinfection Compound Library concentration|Antiinfection Compound Library clinical trial|Antiinfection Compound Library cell assay|Antiinfection Compound Library screening|Antiinfection Compound Library high throughput|Anti-infection Compound high throughput screening| bundles well correlated with the redshift of its UV-vis absorption. PFO emission has completely quenched and being dominant by the DBT emission. This phenomenon could be due to the incorporation of the DBT units into the PFO segments which hence leads to the better conjugation length and chain alignment produced by the PFO-DBT nanorod bundles. Conclusions In the present study, the effect of different spin coating rates on the morphological, structural, and optical properties of PFO-DBT
nanorod bundles is reported. Polymer solution has been demonstrated to have different characteristics and abilities to infiltrate into the cavities at different spin coating rates. Highly
dense PFO-DBT nanorod bundles are obtained at low spin coating rate with enhancement of structural and optical properties. Authors’ information MSF is currently doing his Ph.D. at the University of Malaya. AS and KS are senior lecturers at the Department of Physics, University of Malaya. AS’s and KS’s research interests include the synthesis Methane monooxygenase of nanostructured materials via template-assisted method and applications in organic electronic devices such as sensors and photovoltaic cells. Acknowledgements The authors would like to acknowledge the Ministry of Education Malaysia for the project funding under Fundamental Research Grant Scheme (FP002-2013A) and the University of Malaya High Impact Research Grant UM-MoE (UM.S/625/3/HIR/MoE/SC/26). References 1. Wang H, Xu Y, Tsuboi T, Xu H, Wu Y, Zhang Z, Miao Y, Hao Y, Liu X, Xu B, Huang W: Energy transfer in polyfluorene FG-4592 solubility dmso copolymer used for white-light organic light emitting device. Org Electron 2013, 14:827–838.CrossRef 2. Hou Q, Xu Y, Yang W, Yuan M, Peng J, Cao Y: Novel red-emitting fluorene-based copolymers. J Mater Chem 2002, 12:2887–2892.CrossRef 3. Zhou Q, Hou Q, Zheng L, Deng X, Yu G, Cao Y: Fluorene-based low band-gap copolymers for high performance photovoltaic devices. Appl Phys Lett 2004, 84:1653–1655.CrossRef 4.