09 ± 0.76 cm-1. The Lorentzian bandwidth is mainly contributed by the natural linewidth and partly from the uncertainty of data fitting (0.3 cm-1) and instrumental uncertainty (0.9 cm-1). The natural linewidth is just linked with the phonon lifetimes between interaction levels. On the other hand, the Gaussian bandwidths of the suspended graphene exhibit a much higher than those of the supported graphene. Some mechanisms resulted in
the Gaussian bandwidth broadening and the curve is consistent with the deformation of graphene surface. Other broadening mechanisms are related to the substrate effect and the local heating effect (Figure 5). Figure 5 Bandwidths of G band of the probed area by scanning the mapping points on suspended graphene. By fitting with Voigt function contained (green triangle) Lorentzian part MGCD0103 and (red circle) Gaussian part. Conclusions Spectroscopic investigation on graphene of the interaction between LY2109761 purchase phonons and electrons with the dopant or the substrate reveals a rich source of interesting physics. see more Raman signals of supported
and suspended monolayer graphene were obtained. The peak positions of G bands, and I 2D/I G ratios, and bandwidths of G bands fitted with Voigt profiles were obtained under our analysis, and their different performances of suspended and supported graphene can be used to demonstrate the substrate influences and doping effects on graphene. The Gaussian bandwidths of those separated from Voigt profiles provide a new method to study the influence of the substrate very and doping effect on graphene. Acknowledgments We wish to acknowledge the support of this work by the National Science Council, Taiwan under contact no. NSC
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